Play a match with any character on the Metropolis map, Memorial Station arena (single match or local versus with two controllers). Press Triangle on the Metropolis map to make Memorial Station the starting arena. Push your opponent in the corner and change the time in the PS4 settings. It must be 4:30 am according to the console time to get the trophy. Set the time to 4:30 am manually in the console settings. After changing your console's time, switch back to the game and trigger the level transition to get the "Catch The 4:30 To Metropolis" trophy.
