As you accumulate S-Ranks during your playthrough of thus game, you will start unlocking special EX stages at various points. You will obtain your first 3 EX stages after you S rank 12 normal stages. These stages contain rarer, stronger Pokemon to catch and follow different rules than the main stages. (Defeat the Pokemon in a certain time limit.) You can access these stages by tapping "Extra" on the lower left side of the touch screen. Tap "Main" to return to the normal stage select screen.
Stage | How to unlock
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Stage EX-01: Absol | Earn 12 S-Ranks
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Stage EX-02: Rotom | Earn 12 S-Ranks
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Stage EX-03: Lucario | Earn 12 S-Ranks
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Stage EX-04: Articuno | Earn 20 S-Ranks
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Stage EX-05: Zapdos | Earn 25 S-Ranks
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Stage EX-06: Moltres | Earn 30 S-Ranks
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Stage EX-07: Venusaur | Earn 35 S-Ranks
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Stage EX-08: Blastoise | Earn 40 S-Ranks
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Stage EX-09: Charizard | Earn 45 S-Ranks
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Stage EX-10: Dragonite | Earn 50 S-Ranks
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Stage EX-11: Sceptile | Earn 55 S-Ranks
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Stage EX-12: Blaziken | Earn 60 S-Ranks
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Stage EX-13: Swampert | Earn 65 S-Ranks
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Stage EX-14: Entei | Earn 70 S-Ranks
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Stage EX-15: Suicune | Earn 75 S-Ranks
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Stage EX-16: Raikou | Earn 85 S-Ranks
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Stage EX-17: Heatran | Earn 95 S-Ranks
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Stage EX-18: Xerneas | Earn 100 S-Ranks
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Stage EX-19: Yveltal | Earn 110 S-Ranks
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Stage EX-20: Mewtwo | Earn 150 S-Ranks
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Stage EX-21: Genesect | Earn 180 S-Ranks
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Stage EX-22: Chesnaught | Earn 191 S-Ranks
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Stage EX-23: Delphox | Earn 195 S-Ranks
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Stage EX-24: Greninja | Earn 200 S-Ranks
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Stage EX-25: Terrakion | Earn 215 S-Ranks
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Stage EX-26: Virizion | Earn 215 S-Ranks
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Stage EX-27: Cobalion | Earn 220 S-Ranks
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Stage EX-28: Bisharp | Earn 221 S-Ranks
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Stage EX-29: Gallade | Earn 230 S-Ranks
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Stage EX-30: Goodra | Earn 240 S-Ranks
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Stage EX-31: Luxray | Earn 250 S-Ranks
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Stage EX-32: Malamar | Earn 260 S-Ranks
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Stage EX-33: Mamoswine | Earn 280 S-Ranks
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Stage EX-34: Gliscor | Earn 290 S-Ranks
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Stage EX-35: Porygon-Z | Earn 300 S-Ranks
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Stage EX-36: Walrein | Earn 310 S-Ranks
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Stage EX-37: Honchkrow | Earn 330 S-Ranks
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Stage EX-38: Arcanine | Earn 350 S-Ranks
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Stage EX-39: Yanmega | Earn 360 S-Ranks
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Stage EX-40: Ludicolo | Earn 380 S-Ranks
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Stage EX-41: Hydreigon | Earn 400 S-Ranks
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Note: Earning S-Ranks on the EX stages or SP stages will not count towards your overall total.