Legendary weapon effects are bonuses obtained by defeating certain Legendary enemies.
| Weapon | How to unlock
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| Assassin's | Deal 50% increased damage against humans.
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| Automatic | Automatic fire mode.
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| Berserker's | Deal increased damage depending upon your damage resistance.
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| Bloodied | Deal increased damage depending upon your health.
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| Cavalier's | Take 15% decreased damage while blocking or sprinting.
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| Crippling | Deal 50% more limb damage.
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| Enraging | Your targets frenzy with critical hits.
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| Explosive | Your bullets to explode on impact dealing 15 area of effect damage.
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| Exterminator's | Deal 50% increased damage against Mirelurks and bugs.
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| Freezing | Deal +10 cryo-damage and freeze targets with critical hits.
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| Furious | Deal increased damage with each consecutive hit on the same target.
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| Ghoul Slayer's | Deal 50% increased damage against Ghouls.
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| Hunter's | Deal 50% increased damage against animals.
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| Incendiary | Set targets on fire for +15 damage.
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| Instigating | Deal double damage to full health targets.
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| Irradiated | Deal +50 radiation damage.
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| Junkie's | Deal increased damage depending upon the withdrawal effects.
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| Kneecapper | 20% chance to cripple targets' legs.
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| Lucky Weapon | Deal double damage with critical shots with critical meters refilling 15% faster.
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| Medic's | Heals targets instead of dealing damage to them.
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| Mutant Slayer's | Deal 50% increased damage against Super Mutants.
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| Never Ending | Unlimited ammo capacity.
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| Nimble | 75% faster movement speed while ADS.
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| Nocturnal | Deal increased damage at night and decreased damage during the day.
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| Penetrating | Negate 30% of the target's damage resistance and energy resistance.
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| Plasma Infused | Turn enemies into goo and add +10 points of energy damage.
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| Poisoner's | Poison targets for 10 seconds.
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| Powerful | +25 extra damage.
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| Quickdraw | Decrease Action Points cost by 25%.
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| Rapid | 25% increased rate-of-fire and 15% increased reload speed.
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| Relentless | Refill Action Points with critical hits.
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| Sentinel's | 15% decreased damage while static.
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| Staggering | Stagger enemies with each hit.
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| Stalker's | When not in combat, increases VATS accuracy at the cost of increased Action Points.
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| Troubleshooter's | Deal 50% increased damage against robots.
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| Two Shot | Shoot additional projectiles.
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| VATS Enhanced | Increases VATS hit chances, decreases Action Points cost by 25% and 40%.
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| Violent | Deal 25% damage and limb damage with increasing recoil.
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| Wounding | Bleed target for +25 additional damage.
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