One of the trophies requires players to unlock all movies. Most movies will be unlocked automatically, but some movies can be missed for several reason, like not playing the correct character. Below is the list of unlockable movies. Some movies have some spoilers to the game.
Movie | How to unlock
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"Dial" Rampage | Chapter 4-2
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"Gatekeeper of Hell" | Chapter 2-3
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"Surgeon of Death" | Final Chapter 1
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A New Threat | Chapter 2-4
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Ace and Teach | Chapter 2-4
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Complete Justice | Chapter 2-4
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Continuing the Adventure | Clear chapter 4-3
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Devilish Swordsman of the Triple Sword (Missable) | Chapter 3-2, play as Luffy and face Zorro when he becomes the victory condition(he shows up at enemy main base).
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Even if I Die, I'll Never Kick a Woman | Chapter 3-6
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Feast of "God" | Chapter 3-1
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Fire Fist Ace(Missable) | Chapter 1-4, play as Smoker and meet Ace
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First Son of the Sea Jinbei | Chapter 1-3
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Fist of Love (Missable) | Chapter 1-2, play as Luffy and meet Garp
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I Lose to No One | Chapter 4-2
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It's Now or Never Kuma | Chapter 3-1
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Legendary Marine (Missable) | Chapter 2-4, play as Marco, and don't attack Marine/red faction. Attack pirate/yellow faction until Garp arrives and meet him.
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Light and Thunder | Chapter 4-1
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Love-Love Mellow (Missable) | Chapter 2-3, let Magellan invade home base(where Hancock stays). Don't capture any top area for easier invasion by Magellan.
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Maxim Surfacing | Prologue 1
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Negative Champ (Missable) | Chapter 3-4, play as Perona and defeat Usopp when Moria tries to escape. Defeating Usopp and Robin will clear the stage.
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Opening Movie | Start the game
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Phoenix Marco | Chapter 1-4
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Power of the New Generation vs. Teach | Final Chapter 2
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Prelude to Madness | Prologue 2
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Ragin "Black Leg" | Chapter 3-6
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Raging "Blackbeard" | Final Chapter 2
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Raging "Devil Child" | Chapter 3-3
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Raging "Gatekeeper of Hell" | Chapter 3-5
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Raging "God" | Final Chapter 1
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Raging "Pirate Hunter" | Chapter 3-6
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Raging "Whitebeard" | Chapter 4-2
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Shadow Shadow Fruit User | Chapter 1-3
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Soul King (Missable) | Chapter 3-2, play as Brook, and face Mihawk when he becomes Yellow faction member.
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Straw Hat Pirates vs Teach | Chapter 4-3
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The Battle of Marineford | Chapter 2-4
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The beginning of a New Adventure | Prologue 1
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The Enforcer of Justice | Chapter 2-1
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The Final Battle | Final Chapter 2
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The Grand Finale | Clear Final Chapter 2
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The Legendary Buggy | Chapter 3-5
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The Man Who was Admiral | Chapter 1-1
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The Marines' Greatest War Ability | Chapter 1-2
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The natural enemy of "God" | Prologue 1
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The Nefarious Couple | Chapter 4-1
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The Pirate that Spurs Corpses | Chapter 4-2
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The Power of the Dark Dark Fruit | Chapter 4-2
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The Raging "Iron Man" | Chapter 1-1
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The Sand King | Chapter 2-2
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The Strongest Paramecia | Chapter 4-3
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The World's Greatest Swordsman | Chapter 3-2
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Unexpected Helper | Chapter 2-1
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Want to be a Monster! (Missable) | Chapter 1-4, play as Chopper and score 1000 K.O.
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White Hunter Smoker | Prologue 2
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Whitebeard Dies | Chapter 4-2
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Whitebeard Lives | Chapter 4-2
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