| Character | How to unlock
|
|---|
| Diaochan | Complete Stage 1 and 2 for Wei, then complete her story mode.
|
| Dong Zhuo | Complete Stage 2 for Shu, then complete his story mode.
|
| Lu Bu | Complete Stage 6(x) for Wei, then complete his story mode.
|
| Meng Huo | Complete all kingdoms What If stories, then complete his story mode.
|
| Yuan Shao | Complete Stage 7 for Wei and Stage 3(x) for Shu, then complete his story mode.
|
| Zhang Jiao | Complete Stage 1 for Shu, then complete his story mode.
|
| Zhu Rong | Complete Stage 11(IF)(x) for Shu, then complete her story mode.
|
| Zuo Ci | Complete Wu's What If path, then complete his story mode.
|
