There are two different ways to open up characters. You can either play through battle mode and gain characters as you win, or you can unlock them by earning that character in Story Mode. The Final Stage level can also be opened up by completeing Story Mode.
Unlockable | How to unlock
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Blossom | Win 12 matches in Battle Mode or beat the first level of thePowerpuff Girls level in Story Mode.
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Bubbles | Win 7 Matches in Battle Mode or complete the first mission of the Powerpuff Girls level in Story Mode.
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Captain K'nuckles | Win 3 Matches in Battle Mode or complete the first 2 missions of the Flapjack level in Story Mode.
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Captain Planet | Win 75 matches in Battle mode or complete the Story Mode.
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Father | Win 42 matches in Battle Mode or complete Story Mode.
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Final Level | Complete Story Mode.
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Grim | Win 25 Matches in Battle Mode or beat the first level of the Grim Adventures in Story Mode.
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Mojo Jojjo | Win 63 matches in Battle Mode or complete Story Mode.
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Monkey | Win 18 matches in Battle Mode or complete the first level of Dexter's Lab in Story Mode.
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Samurai Jack | Win 33 matches in Battle Mode or beat the first level of the Samurai Jack stage in Story Mode.
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Vilgax | Win 52 matches in Battle Mode or complete Story Mode.
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