Perform the following actions to unlock more characters.
| Character | How to unlock
|
|---|
| Baraggan Luisenbarn/No.2nd Espada | Resurrection Second Stage/Unlock in Story Mode.
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| Byakuya Kuchiki/Bankai | Unlock in Story Mode.
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| Coyote Starrk/No.1st Espada | Resurrection Second Stage/Unlock in Story Mode.
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| Grimmjow Jaegerjaquez/No. 6 Espada | Resurrection Second Stage/Unlock in Story Mode.
|
| Ichigo Kurosaki/Bankai | Unlocked from the start.
|
| Ichigo Kurosaki/Final Tensa Zangetsu Bankai Form) | Unlock in Story Mode.
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| Ichigo Kurosaki/Hollowfied) | Unlock in Story Mode.
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| Ichimaru Gin | Unlock in Story Mode.
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| Kenpachi Zaraki/Shikai) | Unlock in Story Mode.
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| Kokuto the Bleach Movie 4 villain | Mission Mode.
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| Nnoitra Gilga/No.5th Espada | Resurrection Second Stage/Unlock in Story Mode.
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| Rukia Kuchiki/Shikai | Unlock in Story Mode.
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| Shunsui Kyoraku/Shikai | Unlock in Story Mode.
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| Soi Fon/Shikai | Unlock in Story Mode.
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| Sosuke Aizen/Long Hair Chrysalis Form | Unlock in Story Mode.
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| Tia Harribel/No.3rd Espada | Resurrection Second Stage/Unlock in Story Mode.
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| Toshiro Hitsugaya/Banka | Unlock in Story Mode.
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| Ulquiorra Cifer/No.4th Espada | Resurrection Second Stage/Unlock in Story Mode.
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| Uryu Ishida/Hueco Mundo Arc Appearance | Unlock in Story Mode.
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| Yoruichi Shihoin/Anti-Hierror Armor | Unlock in Story Mode.
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