| Unlock Big Wheel |
| Keep choosing the bad choice when you asked by computer (after beating Tinkerer). |
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| Unlock Black Cat |
| Choose to save Black cat when you fight her (pick the 1st choice when asked by Smythe). |
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| Unlock Hobgoblin |
| Keep choosing the bad choice (the 2nd/3rd choice) before fighting Kraven. |
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| Unlock Jessica Drew |
| Choose to help Shield crew from the symbiote (before you fight with Jessica Drew). |
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| Unlock Luke Cage |
| Make the bad choice (2nd choice) when you asked by a man who say he can divert the train containing symbiote. |
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| Unlock Random Assist |
| You can get mysterio, Night Crawler, Wolverine, Ctylok, Galactus, Hypno Hustler randomly by beating any level or buying the ultra rare powe ups. |
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| Unlock Shocker |
| Choose to free Shocker after defeating him. |
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| Unlock Solidarity |
| Bring shocker to jail (after beating him). |
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| Unlock Storm |
| Keep choosing the good answer when you asked by computer after defeating Tinkerer. |
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