| (Surprise) Aphrodite |
| Defeat Mepisto with Mu in Story mode to unlock (Surprise) Aphrodite. |
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| (Surprise) Camus |
| Defeat Mepisto with Mu in Story mode to unlock (Surprise) Camus. |
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| (Surprise) Mepisto |
| Defeat Mepisto with Seiya in Story mode to unlock (Surprise) Mepisto. |
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| (Surprise) Saga |
| Defeat Mepisto with Mu in Story mode to unlock (Surprise) Saga. |
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| (Surprise) Shura |
| Defeat Mepisto with Mu in Story mode to unlock (Surprise) Shura. |
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| 3D Character Models |
| Successfully complete ten rounds of Eternal Battle mode with any character. That character's 3D model can now be viewd in Zodiac History mode. |
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| Aiacos |
| Follow Aiacos in The Hades mode to unlock Aiacos. |
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| Aiolia |
| Follow Aiolia in Story mode to unlock Aiolia. |
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| Aiolos |
| Win twenty battles in Eternal Battle mode to unlock Aiolos. |
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| Aldebaran |
| Follow Aldebaran in Story mode to unlock Aldebaran. |
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| Aqurius Hyoga |
| Defeat Aqurius Hyoga in Saint Legend mode to unlock Aqurius Hyoga. |
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| Dohko |
| Follow Dohko in Story mode to unlock Dohko. |
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| Eternal Battle Mode |
| Won Saint Legend Mode One Time. |
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| Final Cloth Hyoga |
| Defeat Rhadamanthys with Seiya in The Hades mode to unlock Final Cloth Hyoga. |
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| Final Cloth Ikki |
| Defeat Rhadamanthys with Seiya in The Hades mode to unlock Final Cloth Ikki. |
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| Final Cloth Seiya |
| Defeat Rhadamanthys with Seiya in The Hades mode to unlock Final Cloth Seiya. |
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| Final Cloth Shiryu |
| Defeat Rhadamanthys with Seiya in The Hades mode to unlock Final Cloth Shiryu. |
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| Final Cloth Shun |
| Defeat Rhadamanthys with Seiya in The Hades mode to unlock Final Cloth Shun. |
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| First Cloth Seiya |
| Win Lightning Battle mode with Seiya with at least 5 minutes to unlock First Cloth Seiya. |
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| First Cloth Shiryu |
| Won Lighttining Battle mode with Seiya with at least 5 minutes to unlock First Cloth Shiryu. |
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| Geminisaint |
| Follow Geminisaint in Story mode to unlock Geminisaint. |
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| Gold Aphrodite |
| Defeat Saint Legend mode with (Surplies) Aphrodite to unlock Gold Aphrodite. |
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| Gold Camus |
| Defeat Saint Legend mode with (Surplies) Camus to unlock Gold Camus. |
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| Gold Cloth Hyoga |
| Successfully complete Saint Legend mode with Hyoga to unlock Gold Cloth Hyoga. |
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| Gold Cloth Ikki |
| Successfully complete Saint Legend mode with Ikki to unlock Gold Cloth Ikki. |
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| Gold Cloth Seiya |
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Successfully complete Saint Legend mode with Seiya to unlock Gold Cloth Seiya.
|
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| Gold Cloth Shiryu |
| Successfully complete Saint Legend mode with Shiryu to unlock Gold Cloth Shiryu. |
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| Gold Cloth Shun |
| Successfully complete Saint Legend mode with Shun to unlock Gold Cloth Shun. |
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| Gold Mepisto |
| Defeat Saint Legend mode with (Surplies) Mepisto to unlock Gold Mepisto. |
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| Gold Saga |
| Defeat Saint Legend mode with (Surplies) Saga to unlock Gold Saga. |
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| Gold Shura |
| Defeat Saint Legend mode with (Surplies) Shura to unlock Gold Shura. |
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| Libra Shiryu |
| Defeat Libra Shiryu in Saint Legend mode to unlock Libra Shiryu. |
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| Lighttining Mode |
| Won Saint Legend Mode One Time. |
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| Marin |
| Win five battles in Eternal Battle mode to unlock Marin. |
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| Milo |
| Follow Milo in Story mode to unlock Milo. |
|
| Minos |
| Follow Minos in The Hades mode to unlock Minos. |
|
| Mu |
| Follow Mu in Story mode to unlock Mu. |
|
| Orpheus |
| Defeat Orpheus with Seiya in The Hades mode to unlock Orpheus. |
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| Rhadamanthys |
| Defeat Radamanthys with Mu in The Hades mode to unlock Rhadamanthys. |
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| Sagittarius Seiya |
| Defeat Sagittarius Seiya in Saint Legend mode to unlock Sagittarius Seiya. |
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| Saint Legend Mode |
| Beat The Hades Mode One Time. |
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| Shaina |
| Win ten battles in Eternal Battle mode to unlock Shaina. |
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| Shaka |
| Follow Shaka in Story mode to unlock Shaka. |
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| Shion |
| Defeat Shion with Shiryu in The Hades mode to unlock Shion. |
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| Unlock 3D Character Models In Zodiac History |
| Complete 10 rounds in Eternal Battle Mode with each character to view their 3D character model in Zodiac History Mode. |
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