It's not enough to just meet the requirements for each humanoid class. You must pass the bill associated for each one as well.
Class | How to unlock
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Android | Must beat the main story and be on a 2nd cycle or higher.
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Archer | Healer and Valkyrie level 15.
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Armor Knight | Warrior level 20.
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Battle Suit | Warrior and Armor Knight level 30 and clear Episode 8.
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Beast Master | Warrior and Valkyrie level 20.
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Bouncer | Clear Episode 7 or Armor Knight level 100.
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Gunner | Thief and Skull level 15.
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Lady Samurai | Valkyrie and Archer level 30.
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Magic Knight | Warrior or Valkyrie and Mage or Skull level 30.
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Masked Hero | Thief and Warrior level 25.
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Ninja | Thief and Skull level 30.
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Onmyo Monk | Sorcerer and Ninja level 30.
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Professor | Healer and Onmyo Monk level 20.
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Sorcerer | Skull and Witch level 15.
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