You need to aquire the associated DLC.
Unlockable | How to Unlock
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Angel Class | Score under 145 commands in ITEM World Command Attack (any)
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Aramis | Score under 145 commands in CLASS World Command Attack (any)
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Plenair | In Survival - After collecting 7 level spheres a mystery gate will appear on the next level. Choose "I want the mascot girl"
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Super Hero Aurum | Beat all 4 Raspberyl Chapters
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